An introduction to interface forces Lecturers: Christophe Henry
Transkrypt
An introduction to interface forces Lecturers: Christophe Henry
An introduction to interface forces Lecturers: Christophe Henry (Universite Pierrre Marie Curie, Paris) and Jean-Pierre Minier (Electricite de France, R & D, Chatou) The purpose of the present workshop is to introduce the field of surface forces, both at the fundamental and applied levels. Interface forces are increasingly studied both theoretically and experimentally in various domains, particularly those involving small-scale phenomena (such as in nano-sciences or colloidal particles). During the workshops, student will have a unique opportunity to discuss and exchange views on the issue of surface force. Some exercises (paper and computer) will be proposed to better present and illustrate the subject matter. A background in chemical engineering or physical chemistry will be helpful, although not necessary, for inspiring and fruitful discussions. After a brief introduction of the major concepts in intermolecular and surface forces, the DLVO theory (named after the pioneering work of Derjaguin and Landau, Verwey and Overbeek), which is traditionally used to describe the interaction between two surfaces, will be presented. For that purpose, van der Waals forces will be first highlighted from a theoretical and an experimental point of view, followed by a presentation of the forces acting between two interacting electrostatic double-layers (that form naturally when charged surfaces are immersed into an electrolyte solution). The DLVO theory will then be addressed. The validation of the DLVO theory together with simple applications for colloidal particles will be presented. The limitations of the DLVO theory will then be emphasised as well as some perspectives/theories proposed to remove such limitations, with a special emphasis on recent developments showing the need to account for surface heterogeneities (surface roughness or electrostatic heterogeneities). Projekt „Rozwój interdyscyplinarnych studiów doktoranckich na Politechnice Gdańskiej w zakresie nowoczesnych technologii” jest współfinansowany przez Unię Europejską w ramach Europejskiego Funduszu Społecznego. Finally, an application of surface forces will be presented: the deposition and reentrainment of colloidal particles from surfaces will be addressed to specifically highlight the coupling between hydrodynamic forces and surface forces (which act at two different scales) and to illustrate the influence of small surface features (roughness) on more macroscopic phenomena (here deposition and reentrainment). TERMINY WARSZTATÓW Data Dzień tygodnia Godzina Sala 2012-12-03 Poniedziałek 9.15-11.45 115 IMP PAN 2012-12-05 Środa 8.30-10.00 115 IMP PAN 2012-12-07 Piątek 9.15-11.45 115 IMP PAN Projekt „Rozwój interdyscyplinarnych studiów doktoranckich na Politechnice Gdańskiej w zakresie nowoczesnych technologii” jest współfinansowany przez Unię Europejską w ramach Europejskiego Funduszu Społecznego.