oDc\. o B \oDL .\t. t\.\v
Transkrypt
oDc\. o B \oDL .\t. t\.\v
rol \ltl'YŻUir] l3 tr- 9 oDc\. o B \oDL .\t. t\.\v l i T PZ] .l BLLAŻ IrENrKLLŚz[\VlcŻ B\lt|': synthesis and sP€ctros.opic.haractelization containinBpendant oligoaniline groups lós of polythiophenes Dl lrr]bnd 'DnrugihEnvl.uc) 'd to]ymcn łb.h.d io til. pol!(2,5 DJn .hiin solLLbl! to])'trEś lnih:s iy| ] allllih oFlre.e r!łh th!oPhcn. h $e n] tlt nł) Tlre rcsuldng olm]]v dopd !n inodi. Polvm.l! arc DrnLadÓn oLlgoaniliN.l] 'nj \ Jl b.:c](h!.]| doPcd i||ÓtoMt|Dll ldoFldBo'acid.bJ* lrPd sPe.EoaoD]. t€ l| a: 5Fe.tonoPi. l *qu.n(! o' ihc ,]oll)! p.o.*s ]lc dtr.!*d ń dcia:l\ Polv(r. tylt]]j.F}enc n' : ohgo]nL .ddnnln th.n Śid. !1.'o''l ron ( dof us fnrFohc ttri alsorp 'r 5Pedlum fu'cLi liIg.lłng.ofdr. visibh sP!łfunr K€v $o!d5: l]o vl3 irLlkhlophallł, anilin. .ligoms5' doPi)]B, .L..Eoń.mIE! sp&1lde.do.]nmśh}: ou(iudiv. Polr)r's !Ó!ńenhl nabj ]i| ol. ..Ó.lvmG' -r-.'..!. should l]o bInLy dLffcl.nl f.lvt]bPheńś, '{. 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(^Ldn.h) an,] a ljne (Aldlth) w{eFuilisnbyvi.!!ndrhLLdii,n hai-vFL .Jl Ielchon F!Ł?dUt 2g oi 3 thrcPh.ncElborlilde rilnrw 3 vonoDc(3), N (r rh.fybD,nopr,enr-l) yrncrhyr.r.imiirophcur,r) b.n/e boxyalir.h).d. klto ioi (6rl slowly id,led dFF wbe. Duri'rg thE pro.. d re dr tanperuhm oiihc r.i.h !i!l iÓ.rÓth.n i. nalur. of th..o dud ir e*ńłed ł'irh dietlr],l e(hcl' ,]n.d orcI trllso] Jrd vó.uUD dśhlkdu\jn8 a łv ivłr rB \N!r (cDcL,3oo NrHz, !'pm), rn,3rr), i7r(n,, rH),782(,1H),3$(r, rH) tl (KR|.-') 30ll9 (nn' Jo]o (,"), ló22 G)' 1590 G)' 15]] 1!,)' ]13ł G) 1419 (U)' 1423(r.) ]]r2 (d,l:]3(z]' -- \,1'! )' N (i thi.) JnJ r thiÓPlronil .oNn..iallv .!.i].ijl!' ł 8 PĘla d*djb.d n!Lłłl!in lrl T9Fńll] 'nd tr.r l] ó! Th! fuofubh oI ] tlnoPhcn..albo:valdIh-vJ. 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(id t, tla rrl\C,s d' a,!l.rd d'ai', Thr J'iit to sPi'nc$ di.alioIs.onsistnL NiLh.!] D!]d ro| prD..$e aĘ;cqucnnilo sole rc5c .h tool to]v(2'ałhLc||koc) t Eihon j bF.]ł Llt orid2cd (qln]oid dulxl uniL oinni't |ll.gln.nd śnÓr.b l IDnns <'dane L! h thc .vdrc loł nm UioligÓłjjl]n.l l9] Ii*fugllÓLrllaFs|1hdt FLosous biid D potvF odlLihLophor) homopo (jng oI oliBo ilii,. tDlYl2,! Lhi.ryldr) ni!' rhi flluns5 frA r.urrr) drJ rrts , i. or.ornudir. polr- t]'pl..: .ldtr rol{aDmoglan' oI f2B js pl.Śdto!] l t ił ] uL.!'5 N/nił.i"l] 1tll hlli ł ]lf.fd |dł!,ll 3!]\I'I d[ńsinDhrcolsl|th.b rJsĘ d.a. di.dcd.od. Dotnhilrcsu(s . i geduird. P.r[ 330 rD] (tr th.slb ilułł)d.$notdL51PP.i. ti'k nL5 i! o.sś. nth tr]. p sFDoirns lo Lh. istinguLhłl' !.de Plvmg d!|il8, !]3łlr{ włh .hen ..l io ń. d.doPinB o' żib c1doFbLc) s]].' oLr(2.a..hiffren.) ńEhahńfr ń Hhllh lh. innrc g|ÓuP Ph.nyL.ng k.Pt. H.ł!]g' due n] jĘ dedlodl P.lan7łloo Ddu..: L]u.n.coItlkold nnt(fśs.l F.xnliŻ.d t] a F.LINIEPYr0rrr .a] b.hivloI' howcvcr jt5 oldatl'. doFirg śl ś* slig]]tlv lo\'el pÓe|hłls (E = 0a5 .I d.pnrgs usnlg ri/rJl rtr,li, r.ls.d ,y 13 r7 I ii '.. l]ne (]_. = !06{ nn) lł] th. oiiJ ion oI oligoanil'n. sidĆ grcuPs lo *łB bl di.al dt ń Ć t]ienL.omplet t]iiei)le|e lhaij] n] spiilśs lLi. ioN (biPo ioaś and w! lrr! srrdrsr<r, b1 (p.rv! gDanilinłhjoFhlń8l' lr 3 alkylthioPhenB, ł n$L ń ] (trlsz4tz 8iE l,lloń.\ lbcmo]yti J' tJ] d.] c,odłoul L,9ob.1'[] r hh hr,l olś'rd(ic'r, 1ee7,*.r 3 lhlDG.DLd^ C 'zl.lLy,F.|!',F!rel. rcn\r,JirlLr o. ono !j. |iilitrJ fj0fi'lllfl,!.i !.|t'iinnał'J/(!Ncn lrli]l s Ł. Dlił!.i; N!r 9 rjog T, hg l.s o, Wdmuł].m ]dnrJ F M@ łłrnr. ! !)94' Ż7' ó.i3 Bo!!l T'śhJ v l, au hld s'.o.hł