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MATERIAL SAFETY DATA SHEET
Conforms to (UE) Nr 453/2010
Izopianol 40/30 C/01
Date of issue: 01.04.2011 r
SECTION 1. Product identification and company identification
1.1. Substance name : Izopianol 40/30 C/01
1.2. Use of the substance/preparation: Izopianol 40/30 C/01 is two component system for producing
rigid polyurethane foam.
1.3. Producer identification
Purinova Sp. z o. o.
85 -825 Bydgoszcz ul. Wojska Polskiego 65
tel. 014 631 91 00 fax. 014 631 91 18
Person responsible for the Safety Data Sheet
[email protected]
1.4. Emergency telephone
112
SECTION 2. Hazards identification
2.1 Classification of the substance or preparation
Classification in accordance with Regulation (EC) No 1272/2008
Acute Tox. 4,
H302 Harmful if swallowed.
Classification in accordance with Regulation 67/548/EEC or 1999/45/EC
Xn;
R22 Harmful if swallowed.
2.2 Label elements
Warning
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Purinova Sp. z o.o.
ul. Wojska Polskiego 65, 85-825 Bydgoszcz, Poland
Tel: +48 14 6319100, Fax: +48 14 6319118
email: [email protected]
http://www.purinova.com
Sąd Rejonowy Bydgoszcz
XIII Wydział Gospodarczy
KRS: 0000269659
NIP: 9930501149
Kapitał zakładowy: 3.000.000 PLN
H302: Harmful if swallowed.
P264 Wash hand thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
2.3 Other hazards
No data available
SECTION 3. Elements of marking
3.1 Substances
Not applicable
3.2 Mixtures
Hazardous components
NR WE
Nr CAS
Tris(2-chloro-1-methylethyl)
phosphate
Cyclohexyldimethylamine
237158-7
202715-5
13674-845
98-94-2
Hexanoic acid, 2-ethyl-,
potassium salt
-
% (by
weight)
< 17%
< 0,5%
3164-85-0 < 0,15%
221-625-7
Classification
Acute Tox. 4 H302
Xn; R22
Flam. Liq. 3 H226
R10
Skin Corr. 1B H314
R34 R20/21
Acute Tox. Inha 3 H331
/22
Acute Tox. Derm 3 H311
R41
Acute Tox. Oral 3 H301
Eye Dam 1 H318
Eye Dam., 1, H318
Xi; R41 R43
Skin Sens., 1, H317
Repr. Cat.
Repr., 2, H361d
3; R63
SECTION 4. First aid measures
4.1 Description of first aid measures
If inhaled:
Inhalation Not expected to present a significant inhalation hazard under anticipated conditions of
normal use. At longest contact remove person to fresh air Keep him quiet and warm. Apply artificial
respiration if necessary and get medical attention immediately.
Skin contact
Not expected to present a significant skin hazard under anticipated conditions of normal use. Remove
contaminated clothing as needed, and wash skin thoroughly with soap and water. Do not use solvents.
Get medical attention if irritation occurs.
Eye contact
In case of eye contact, immediately rinse with clean water for 10-20 minutes. Obtain medical attention.
4.2 Most important symptoms and effects, both acute and delayed :
No data available
Page 2/7
Purinova Sp. z o.o.
Tel: +48 14 6319100, Fax: +48 14 6319118
KRS: 0000269659
NIP: 9930501149
4.3 Indication of any immediate medical attention and special treatment needed:
If swallowed medical advice is required.
SECTION 5. Firefighting measures
5.1 Extinguishing media
Product is not classified as flammable.
Extinguishing media :carbon dioxide, dry chemicals, foam
5.2 Special hazards arising from the mixture :
Fire can produce dense smoke containing hazardous products of combustion (carbon oxides).
Exposure to decomposition product may be hazardous. Do not enter fire area without proper
protection. Fight fire from safe distance - protected location. Respiratory protection equipment
may be required.
5.3 Advice for firefighters :
Wear full firefighting turn-out gear (full Bunker gear), and respiratory protection (SCBA). DO NOT
direct a solid stream of water or foam into hot, burning pools of liquid since this may cause frothing
and increase fire intensity. Frothing can be violent and possibly endanger any firefighter standing too
close to the burning liquid. Use water spray to cool fire exposed containers and structures until fire is
out if it can be done with minimal risk. Avoid spreading burning material with water used for cooling
purposes.
SECTION 6. Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures:
Slippery walking, spread granular cover or soak up.
6.2 Environmental precautions:
Prevent spreading over a wide area (e.g. by containment or oil barriers). Do not let product
enterdrains. Do not flush into surface water or sanitary sewer system.
6.3 Methods and material for containment and cleaning up:
Keep in suitable, closed containers for disposal. Soak up with inert absorbent material (e.g. sand,
silica gel, acid binder, universal binder, sawdust).
6.4 Reference to other sections
No data available
SECTION 7. Handling and storage
7.1 Precautions for safe handling
Prevent unauthorized access. To avoid contact with the skin and the eyes Wear recommended
personal protective equipment. Containers, which were opened, they ought to be the hermetically
closed and held in the position which prevents leakage.
7.2 Conditions for safe storage, including any incompatibilities:
Product is hygroscopic. Keep drums or containers tightly closed to prevent contamination. Store
between 10 0C and 25 0C dry and ventilated place.Product is hygroscopic. Keep drums or containers
tightly closed to prevent contamination. Store between 10 0C and 25 0C dry and ventilated place.
Page 3/7
Purinova Sp. z o.o.
Tel: +48 14 6319100, Fax: +48 14 6319118
KRS: 0000269659
NIP: 9930501149
7.3 Specific end use(s)
Not applicable
SECTION 8. Exposure controls/personal protection
8.1 Control parameters
No data available
8.2 Individual protection measures:
No data available
SECTION 9. Physical and chemical properties
9.1 Information on basic physical and chemical properties:
pH
No data available
Boiling point/boiling range
No data available
Flash point
No data available
Vapour pressure
No data available
Vapour pressure
No data available
Density
1.1 – 1.2 g/cm3 (25°C)
Solubility
Water, alcohol, aldehyde, ether, aromatic hydrocarbons.
Water solubility
Soluble
Partition coefficient: n-octanol/water
No data available
Viscosity
200 - 400 mPas (25°C)
9.2 Other information
Not applicable
SECTION 10. Stability and reactivity
10.1 Reactivity
Slightly reactivity
10.2 Chemical stability
Hygroscopic
10.3 Possibility of hazardous reactions
Not applicable
10.4 Conditions to avoid
Not applicable
10.5 Incompatible materials
Strong oxidizing agents
Page 4/7
Purinova Sp. z o.o.
Tel: +48 14 6319100, Fax: +48 14 6319118
KRS: 0000269659
NIP: 9930501149
10.6 Hazardous decomposition products
Not applicable
SECTION 11. Toxicological information
Experimental data about toxicological information is not available.
Data about component ( Tris(2-chloro-1-methylethyl) phosphate)
Acute toxicity
Acute oral toxicity
- LD rat < 2000 mg/kg
Acute dermal toxicity
- LD50 rabbit > 5000 mg/kg
- LD50 rat > 2000 mg/kg
Acute inhalational toxicity
- LD50 > 7mg/l (4h)
Serious eye damage/ irritation
Not irritant
Skin corrosion/irritation
Not irritant
Respiratory or skin sensitisation
Not a sensitizer
Mutagenicity
Not mutagenic by the Ames Test Mutagenic in the mouse
lymphoma L5178Y test system. Non genotoxic in an in-vivo
micronucleus test in mice
Carcinogenicity
Not classified by IARC. Not included in NTP 11th Report on
Carcinogens
Reproductive toxicity
In a two-generation oral reproductive toxicity study a LOAEL
of 99 mg/kg/day is derived for effects on fertility and for
developmental toxicity
Neurotoxicity
Not neurotoxic
Specific Target Organ Toxicity (STOT) - Single exposure
No effects on specific target organs have been identified
Specific Target Organ Toxicity (STOT) - Repeat exposure
NOEL >20,000 ppm (13 weeks, oral, rat)
Aspiration hazard
Not expected to occur
SECTION 12. Ecological information
Experimental data about ecological information is not available.
Data about component ( Tris(2-chloro-1-methylethyl) phosphate)
12.1 Toxicity
Aquatic toxicity :
- 96 Hour - LC50, Fish 56.2 mg/L
Page 5/7
Purinova Sp. z o.o.
Tel: +48 14 6319100, Fax: +48 14 6319118
KRS: 0000269659
NIP: 9930501149
- 48 Hour - EC50, Daphnia magna 131 mg/L
- 72 Hour-EC50, Freshwater algae 82 mg/L
Chronic toxicity The No Observed Effect Concentration (NOEC) in Daphnia magna is 32 mg/l.
12.2 Persistence and
degradability
Not readily biodegradable
Inherently biodegradable
12.3 Bioaccumulative potential
Measured BCF of 0.8- <14
Not bioaccumulative
12.4 Mobility in soil
Based on measured results the adsorption coefficient for TCPP
is derived to be 174, indicating a moderate adsorption potential.
12.5 Results of PBT and vPvB
assessment
Does not meet the criteria for PBT or vPvB assessment
12.6 Other adverse effects
Germany, water endangering classes (WGK) 1
SECTION 13. Disposal considerations
Product
Allocation of a waste code number, according to the European Waste Catalogue, should be carried
out in agreement with the regional waste disposal company.
Packaging
Residuals must be removed from packaging and when emptied completely disposed of in accordance
with the regulations for waste removal. Incompletely emptied packaging must be disposed of in the
form of disposal specified by the regional disposer.
SECTION 14. Transport information
14.1 UN number (ONZ)
Not applicable
14.2 UN proper shipping name
Not applicable
14.3 Transport hazard class(es)
Not applicable
14.4 Packing group
Not applicable
14.5 Environmental hazards
Not applicable
14.6 Special precautions for user
Not applicable
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15. Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
REGULATION (EC) No 1907/2006 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL
of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Page 6/7
Purinova Sp. z o.o.
Tel: +48 14 6319100, Fax: +48 14 6319118
KRS: 0000269659
NIP: 9930501149
Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC
and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as
well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC
and 2000/21/EC
COMMISSION REGULATION (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No
1907/2006 of the European Parliament and of the Council on the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH)
REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL
of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending
and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
15.2 Chemical safety assessment
Not applicable
SECTION 16. Other information
Given information in the Material Safety Data Sheet result from current state of our knowledge and
experiences. They do not determine the safeguard of the properties of product or qualitative
specification and they cannot be base to the complaint. Product ought to be transported, stored and
applied in accordance with the obligatory rules.
Submitted information cannot have applications for the mixtures of product with other matters. Usage
of given information, and the application of product, are not controllable by producer. The term of
safety conditions of application is duty of the user.
This is a new version of the sheet adapted to REACH legislation.
Page7/7
Purinova Sp. z o.o.
Tel: +48 14 6319100, Fax: +48 14 6319118
KRS: 0000269659
NIP: 9930501149
Purinova Sp. z o.o.
Tel: +48 14 6319100, Fax: +48 14 6319118
KRS: 0000269659
NIP: 9930501149

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