Cover - Journal of Achievements in Materials and Manufacturing
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Cover - Journal of Achievements in Materials and Manufacturing
ISSN 1734-8412 Editor-in-Chief Prof. Leszek A. Dobrzański http://www.journalamme.org Volume 29 • Issue 1 • July 2008 PUBLISHED SINCE 1992 formerly as Proceedings on of Achievements in Materials and Manufacturing Engineering Achievements in Mechanical and Materials Engineering Published monthly as the organ of the World Academy of Materials and Manufacturing Engineering Editor-in-Chief Editorial Board Prof. Leszek A. Dobrzaƒski - Gliwice, Poland Prof. Prof. Prof. Prof. Prof. Prof. Prof. Prof. Prof. Prof. Prof. Prof. Prof. Prof. Prof. Prof. Prof. Prof. Prof. Prof. Prof. Prof. Prof. Prof. Prof. Prof. Prof. Prof. Prof. Prof. Prof. Prof. Prof. Prof. Prof. Prof. Prof. Prof. Prof. Prof. Prof. Prof. Prof. Deputies Editor-in-Chief South America Prof. Maria Helena Robert - Campinas, Brazil North America Prof. George Totten - Portland, USA Europe Prof. Jose Manuel Torralba - Madrid, Spain Asia Prof. Yong Taek Im - Daejeon, South Korea Australia Prof. Kanaka Durga Vara Prasad Yarlagadda - Brisbane, Australia Africa Prof. Abdalla Wifi - Cairo, Egypt Associate Editors Dr Mirosław Bonek Dr Małgorzata Drak Dr Klaudiusz Gołombek Ms Marzena Kraszewska, MA Dr Janusz Madejski Dr Daniel Pakuła Editorial Assistance Dr Magdalena Polok-Rubiniec Dr Anna Włodarczyk-Fligier Dr Bogusław Zi´bowicz Ms Barbara Doł˝aƒska, MSc Ms Justyna Hajduczek, MSc Reading Direct Dr Adam Polok Mr Piotr Zarychta, MSc Reading Direct 2 This journal is a part of Reading Direct, the free of charge alerting service which sends tables of contents by e-mail for this journal and in the promotion period also the full texts of papers. You can register to Reading Direct at http://www.journalamme.org Gilmar Batalha - Sao Paulo, Brazil Emin Bayraktar - St-Ouen, France Milan Brandt - Swinburne, Australia Tara Chandra - Wollongong, Australia Antonio Cuhna - Guimaraes, Portugal Marek Dollar - Oxford, Ohio, USA J. Paulo Davim - Aveiro, Portugal Sabahudin Ekinoviç - Zenica, Bosnia and Herzegovina Renato Esposito - Naples, Italy Spilios Fassois - Patras, Greece Swadhin Ghosh - Rösrath, Germany Janez Grum - Ljubljana, Slovenia Toshio Haga - Osaka, Japan Abdel Magid Hamouda - Doha, Qatar Stuart Hampshire - Limerick, Ireland Lauri Holappa - Espoo, Finland John Barry Hull - Nottingham, United Kingdom Mark James Jackson - West Lafayette, Indiana, USA Krzysztof Jemielniak - Warsaw, Poland Jerzy J´drzejewski - Wroc∏aw, Poland Yosef Katz - Beer Sheva, Israel Andrzej Klimpel - Gliwice, Poland Ivars Knets - Riga, Latvia Janez Kopac - Ljubljana, Slovenia Karl Kuzman - Ljubljana, Slovenia Anatolij Kuzmenko - Khmielnitsky, Ukraine Petr Louda - Liberec, Czech Republic Stanis∏aw Mitura - ¸ódê, Poland Andrew Nee - Singapore, Singapore Jerzy Nowacki - Szczecin, Poland Abraham Ogwu - Paisley, United Kingdom Fusheng Pan - Chongqing, China Mario Rosso - Turin, Italy Antonio Sousa - Fredericton, NB, Canada Božo Smoljan - Rijeka, Croatia Jerry Sokolowski - Windsor, Ontario, Canada Zinovij Stotsko - Lviv, Ukraine Jerzy Âwider - Gliwice, Poland Ming-Jen Tan - Singapore, Singapore Boris Tomov - Rousse, Bulgaria Marcel Van De Voorde - Brussels, Belgium Senay Yalcin - Istambul, Turkey Bekir Sam Yilbas - Dhahran, Saudi Arabia of Achievements in Materials and Manufacturing Engineering Patronage Cover story Silicon is the main material on which phodeveloptovoltaics depends. It ment belongs to n-type donor semiconductors or p-type accpetor ones, depending on its Editor-in-Chief Prof. Leszek A. Dobrzański Volume 29 • Issue 1 • July 2008 admixtures. The pentavalent donor elements atoms introduced into silicon (but also into germanium), e.g., P or As, or with a bigger number of palence electrons, bond with Si (or Ge) atoms with four electrons only, introducing the remaining excess electrons to the semiconductor conduction band, demonstrating the elektron conduction. The conduction electrons move under the influence of the applied electric field causing charge transfer, and releasing of http://www.journalamme.org electrons is favoured by temperature increase, Chile conductivity gets bigger along with the doping agents atoms concentration increase. Atoms of the trivalent acceptor elements, e.g., B or Al, or with a smaller number of valence electrons introduce the unfilled energy state called holes to the valence band, so the electrons from this band are excited to the acceptor state with energy higher than the upper palence band limit. The hole conduction grows also with the increase of temperature and concentration of the dope atoms. The photovoltaic effect occurring in silicon and in some other semiconductors consists in generating a pair of current charge carriers electron-hole in the semiconductor by the solar radiation photons with the energy exceeding the gap of energy levels of this semiconductor. The electric charge developed this way may undergo recombination due to which solar energy is converted into heat energy which should be counteracted. The value of the photovoltaic current depends, among others, on the power of the solar radiation fetching at Earth, area of the illuminated surface, and also on the type of material in which the radiation energy absorption takes place. The intensive research on mastering the photovoltaic cells technology have brought their efficiency to more than 20%. Photons of the electromagnetic radiation falling onto the semiconductor surface can be absorbed by it, participating in the photovoltaic effect when the remaining two phenomena of reflecting the photons from the surface or their transition through the material are useless from the photovoltaics point of view. If the photon energy is significantly higher than the semiconductor energy gap width then energy of this surplus is converted into heat energy and is dissipated. Because of the energy gap specific for silicon about 44% of the solar radiation energy fetched up can be used. Materials with a bigger energy gap generate a higher photoelectrical voltage; whereas, materials with a smaller energy gap use bigger part of the solar spectrum and provide a higher short-circuit current. Silicon is characteristic of a skew energy gap; therefore, photons participate in electron transition from the valence band to the conduction band and one or more phonons is absorbed or emitted. In semiconductors with such gap the life of carriers is longer than in case of those which have the straight energy gap. In USA photovoltaic arrays have been used to day mainly on a small scale, for the light roadside signs or as rooftop panels to provide energy for homes or commercial buildings. An example are the solar panels on the buildings in the research giant Google campus, which are expected to provide around 1,600 kW/h of the electricity. The bird’s-eye view of this campus is shown in the first small photo on this Issue cover. However, the photovoltaic power stations develop very intensively in the last years – also in USA. The largest solar power plant in North America was opened in December 2007, shown in the big photo on this Issue cover. This power station provides electricity to Nellis Air Force Base in the Nevada desert in USA. Nellis, which is outside Las Vegas, is devoting ca. 56 ha to a massive photovoltaic array with panels of silicon wafers that rotate to follow the sun across the sky and generate electricity. The plant is capable totally of producing 15 MW of the electricity, enough to provide 30% of the electric needs on the Nellis Air Force Base, where 12,000 people work and 7,215 people live. The Air Force expects to save $1 million a year in lower electric bills and to use the plant to demonstrate it is boldly advancing the use of renewable energy technology. ISSN 1734-8412 World Academy of Materials and Manufacturing Engineering Polish Academy of Sciences, Committee of Materials Science, Section of Metallic Materials International Federation of Heat Treatment and Surface Engineering Association of Computational Materials Science and Surface Engineering Institute of Engineering Materials and Biomaterials of Silesian University of Technology, Gliwice, Poland Financial support In 2008 the publication of the Journal is financially supported by the Ministry of Science and Higher Education in Poland. Abstracting services This Journal is sent to individual receivers from ca. 50 countries of the world and is delivered to the National Libraries and Universities and also to other scientific institutions in ca. 50 countries of the world. The electronic system of Reading Direct allows to access to the electronic version of that journal on-line, in the promotional period free of charge. This Journal is included in the reference list of the Polish Ministry of Science and Higher Education (6 points). The procedure leading to the citation of that journal by Abstracting Services has already begun. Journal Registration The Journal is registered by the Civil Department of the District Court in Gliwice, Poland at number 279 Publisher Gliwice 44-100, Poland ul. S. Konarskiego 18a/366 e-mail: [email protected] Bank account: Stowarzyszenie Komputerowej Nauki o Materia∏ach i In˝ynierii Powierzchni Bank name: ING Bank Âlàski Bank address: ul. Zwyci´stwa 28, 44-100 Gliwice, Poland Account number/ IBAN CODE: PL76105012981000002300809767 Swift code: INGBPLPW Gliwice – Campinas – Portland – Madrid – Daejeon – Brisbane – Cairo ® 2008 International OCSCO World Press. All rights reserved The paper used for this Journal meets the requirements of acid-free paper Printed in Poland 3