i. ::!łi."
Transkrypt
i. ::!łi."
POLIMERY 2002, 17, nr t9 1 ! f!:T !1 i. :! -iE ?c +:Ę :!!ó E. Y;: iłił..: ::!łi." =L!T::! €E;ł:;i G) EP: !:E- tE li I : Ż.? ! i: l !9 s;i :d !J{,-Etid!"! [; 1li ]a;!it ! j\;,' I .'i, : -_: r- Żaż EE! l,I g $ s ql iB s ! :i i:a t+ E+ e ! I E :e POL]\4ERY 2002, 20 mand /. (,4., = 1.)is accordhg tr) c1cf.33 So\.nljng. Tn contlast 1o lhe inj€ction noulding Ploccs\, whjch is l1_ l\'a}'s nonsiaiionałv, ihe flo1\. oI n orrlalion during lhis proccss .an bĆ .lchi.\ cd to bc a statioInł. [1, ]6] Bl'using defiritions 7 rd 3.1 onc can pass fi,)m the tunciional to the hierar.hi.al con.epi oI the s\'slem. ln : i;'1 ' |ó.' and nrje.lion ale uniiied' ihe il1iec|ion moul.ljr1g s)'stĆn, lvhjch rna!'be at the sJrie tirne.egarded a5 the tru€ syslem (dels. 1.1 nnd 35) consi\ts Df thr.c sub's\,st.ms These sut}5}'stem5, accordjng 1o det 2a .an be i1 thĆ sane time regarded as the sYst.ms with th. sanc athl buies, iun.tions and caiegDries as ihe n1je.1lon rnoul dińg s)'stem. r\ccording to dcf lit rls 11-33 .n.1 37 oI ihe jnj.ciiol molridjn8 s\.sienr, llie inje.lion moulding system, is lor instil\.e, the mpcr svstcn, nnd thc nrjcc' lion mouldlng nachine or mould is a sub sr'stern. l"r:., "r -r rnd iifornLltiDn conncctiois ar-rd spati.l .nd te por.rl relalions. Each s]'siem is srLroundc.l b\' th. t..lmjcil en\ ironrr$t oi a thing. Ac.ordjng io (dei 1al the s,vslem of trrget c\isls only 1vh.n thc Bi\'cn svśtcrrrĆontajns the set ol sub svs1etns (o) and lhe se1 oi le]auL]ns (i)' In the injĆctioi rnouLdDs c\ist th. followinB sub's\st.n. of aunctjols: preparn lion oI nailer (cu), injeclion (cL:) ic,, Cr = c,), rn(-.u1Ll]ng (C1) ancl re.clinrg of prescibe.l lemperalures (Crl. Rcacl' o.J- nB thc }.I.s. .l rel' ald nou]d (C;:) (c' L.cL1 r... t.n}r.ralrrres i5 !rt€nded = c]]L i.-t. 'a 1o ., o. = ll 14,.4.,C,1 SnnultaneoLts\', thcrc .\ist thc,icts of rel.tiLrns: rell lion of indifie.€ncP' re]'iio| ol inslrumeni.ltior1 .1ń.1 r.' lation oi prelercnce. (11 Florn the (dei' 1ó) Io]]D\fs lha1 1he re]a1ion of ]Idifi.' rcncc.xists bcttlcrn the li,,(a,,,41.: targets le.!-, ^ L-.: (51 T}e lne.xling oI equation (]) js that ii iśnot jnPoltarlt wheńer th€ Pręs.ńbed ten1Penture of PrePa]aiion Lrnii ol mchcJ ńrst' Fi\'e jnslru]nenia] re]alions n1av be iden1ilied (dĆl' 16). First, it is rlcccssarv hr r.ach th. pr.scribcd ktpemtul€ of the PlePalition ].nit and thćn thc onc of th. L\e necess.5' lelnPeralLrc lieLd nl the mould i\ ł.,(a,,a, )ą a.,-l c ł' ](a,:c,,]<] a':ł ar i6] i'] Strictll, the qlrasLst.tiolar) tclrp!:r.tL e iield in nou1c1 can bc lca.he.L ,]nl! aft€l a sefela] c)'.les, bec.lusĆ the hjected lnaiter lrnnslers inio a mould a cerl.rin ,t!L antiq, of he.rt. Therelorc, this \h.rl] be considered a star' nr I rroul.L icnrperalure fi.ld th. on., rcprpsprlted b\. '.,i ir - h". ir -.r....n; tr..ror crcl., efabling th. nouldnls to be proclu.ed \r'ith a lolrer, but a.ccptable quality. In thi\ .a,ie the jnstrumell trL rel.iiorl .on b. rrritten as lollolvsl the P. j(a,,ra,l-..'. + 4, lE) ThĆ func1ion of rrr.uldnrg caluoi be fu]fi]]cd b.i(!e ih€ iu1lction oi jl1je.tion js ft]lfjlL']Ll: rl,,rLa:a:)P a,r J a lel 'ĄIteI noulL]ine has bccn .onPlcleL]- ihe s1n|iona .r ir-l I ' ' , |,;(a,ai,,lri C. +.C,. .Ąfter 1ile lirst inje.Lion of nnttel into the rnort]d, \om. tnle is n...ssaN to rei.h n qunsi slali.l-Lnrv ii\n- i ' l l ln r. t'"i' tarrt to ha\'e thc co1djtions ior injectlI ńl]fi]]el], raiher thrll th. qlrasi-statio)larv iemperiiure fielLl in moul,l: il, LL ..4:.r e=CL + t-.,: il]l Based uP.. ihe re]alions foll(l\.nrg deis' Ló, Ls, 19, th. s.t of relatil \ ld.l. 15) .an be writt.n in th. fonn: 1l:i l', ,,.. ,1,,.1.,lr.t l jii.c_ .Ą.cordnls lo del. 2Lr th. chJnl oi talgel l. lol tjon nlolrlding s]-sien1 rnl\ b. Li.fnl.d .s: r. ={1.,,1, (131 statjrrg te]nPera1ulę iie]d, quasi 51a11ondrt'tel!ĘeriltuLe liĆ]d) Ih. st.rltng tcmprraturc ficl.l thr moul.l can be described as: C': tj)18 .J7, Cenclal definition of inj€ction mou]din8 Bv Jufnulg the chah targets- the order Lrf inlli\ i.lu.r] ńrIclion.L.\'oloPn1eni is fix.LL' Thc defnrition ol t]-Lc ch.1in ol iargets, .1ś a5 Lhe .leiin]1ic]n oi nuni Paltjil '!c]l elnlnes 1he g.nIal dPfnlilion ńur.ti.,ns of thc nrorL]d, of n1iectiN nrou]dn1B and th€ deiinilion ol ilrfornatjor il$r ro be Jctermnled ll, l5l. In fonr!Laling ;L gcn.ral dellniiion of injecti.n rnoULLlnlg, il is r-Lccpss.rry 1o find r paranretp. ihal reduces al1 the obsen.d Ir.ttpr io a cornn)on d.rloni|.tor. Accor dinB to Lenk, this p.rrarn!ter j. slipar viscosity [5]. L..k bcLie(es 1hat tl'l. ]nain str1e of a]] milttcr iśljqljd, and thal th. solid Jrld gL,rsc.us states are onh. spe.iaL f.rns of thc liqir stat.. Adopllon ol this Yic\!, basd .nrong othcr thngs on th. ft]Ż/v sei Łheo( (IuzŻY Y.rriablcs), rnakps the adoptjlrf ol a generdl dcfniitnD of jnje.lion rn'rlrldjng ol rlLitt.r possible. Tl\e definition starts fr.rr lhe ńt]1.ti{'i !-.i pro.edul.s and Ll.sclibes 1he l]o'L or rnaller anLl energ\. as a pro..ss. Inje.lion nro!lLling (die castug) of rnatrpr is all o\'Ćl Prcssure .\..]ic nodc of P(r.eL]ure oi Prilnan'sha' t:.'1. tĆ.l into a ca\'it\ with the Plcs.ribed lernPeratul.. ihc prodltcl. a nroul.llng, rl ilh a delincd shap. an.l proper tiĆs is otulle.L bf gciatnrn anLl/or .oo]ins, some kiid of .eactions. such as Pollrneris.lion and./ or crossljnking POLIMERY 2002, 47, nr 1 21 or some other mode/ and it can bc subsequcntly demo u]d€d' Th€ deflnliion of ]]lformaiion no1v is: C]oselooP con' h'ol ol i.jectjon mouldjng Process can be ac1riev€d b\' mation Ilorv ol onc function ('3., injeciion) must be cor rected b,v interactilrn of other functiorr (this can be realjsed .*', r'iih the aid of one sup€rordinate l€tu]ntoa' It mrEt be ponlted out that both thcse ciefiniiions are jnlormalicallv ver.v spnrse owing to the very high lcvcL ol modcl's abstractiol. For this reason, lor each single Procedure an aPPropńate defir-]jtjon rnlst be worked out. As examples, lve Bile 1\\.o definitions, first, fo, injection molrlding proccss for thcrmoplasiic melts, and s€cond' f.]r reaction nljection mou]ding of jnte8la] Po]'v_ urethane ioamed parts ll5l. From th€ Point of viel\' of i]olv of matter and enelg}' (ploccss dcfir1itiol), thc nljcction mouldhg ol th€rmo p]astic n€lts is a hith plessL]Ie cvc]ic ode of Plocedu_ rc ol (nol1 reacti\'c) Primaly shaPing' A th€rmoP]asti. nlelt with tl-Le ncccssarv shcar !'iscositv is injeciecl into a .avitv with the Pr€scribed t€mPefatule' The product, a moulding, rlith the defined shape and properties, is obtanled b,v gelation and,/oL cooljng, and it can subse quentl_v bc dcmoulclcd. Th€ Plocess definition of rcaction injectjon moul.ljng of inicBral PoLlurethane fo.ned Palis ma-v be lfr]it€n as a low-PressLfe c'vc]ic mode ol ProĆcdurc of rcactivc Prnnalv shaPjng' Th€ comPound of nati€rs 1\.ith the n€c€ssal)' shear Yisc(jsitv is injccted n1to a ca\'it! \fith the prescrib€d t€mperatLf€' The ploduct, a mouldjng, \\.ith the defincd shape and properties is obiained b! polladditbn and cross-linkrr1g, accornparljcd bl foantug, and it can subsequentl_v be clemoulded. coNcŁUsloNs The p.rrticular ! aluc of svstcnjc approach is ihat ii points it the universalit,v of occ rrence and teneratcs questjons \rhich othertlise would ha|c nc\cr been ask€d' The s)'st€nic aPprcach a]]ows a rangc ol Vcr}_ meanlnsfu1 concepiions anc1 iheories io be creat€d and included like cybernetics, infonnatiorl tcchnologv, ccoio$', .t.. In resolving single, actual problems, the syste- mic approach offers a general conception basc, ihe me thodolo8,v of desiBn and improvement of svstcns, scientific m€thod, .i.' 13]' The main purPos€ of th€ Plesent discussiolli5 io reach bcticr rjnderstanding of ihe process€s that takc Place a in dif€lent s}'si€ms, to make the )1ccessal,v 8e]rera]isa' tions, and tlr fomlu1ate g€n€Ial ru]es' To lea]jse this reqtirenrcr1i, on th€ basis oi c€Itain the' oreiical .onsjdcration, injecuon rnoulding of mntier has bccn syst€matica1Lv ana]vsed' R]]EERENCES 1. Ćatić I', R.os P'' RaziN'' 2. 3' I1]tefiatiada| Polyner Pro L'.sstrs 1988, 3,198. Catić l', Razi RoPoh] N':/rl'ste c.: "Eine |1d Ka,'tschu]ś 1987 , 34, ai syst€mth€orie deL Tcchnik"' Hansers Publisbers, Munich, Vienna'1979. ,1. Kin O., Pelikan P.r "Kibcmctika u ekonomljf', Savlcmena adminjstracija, Beograd 19ó7, 57_1t]5' 5' LĆnk R.| ''Rheologic cler Kunstsioffe", Hansel Pu_ blishers, Nfunich, Vjcnna 1971, p. 1 -4. C.iić I.: Po]nl./i 1988, 9' 279' catić I', Marince] D': N'Iou]d as a Baich Reactor' 4Jth ANIEC, Dal]as, Nlav 7' to 11', 1990, P. 69H99' Catić l', sPanićek D.I Po]r11e]'i 199a,I,295. DIN E5S0. Berlin 197,1. Ćatić ]'] Polin.ri l987,8,295' Kiiufer H.: Arbeiten n t Kunstsblfer,, \rcrarbe itun8. Band 2, 2. Auf, Springcr Verlag, Berlin, Heidelberg, NelvYork 1981, p.27. Cntić i.: Polvn1el Proccsslng xr the 2lst Centurv, LLIT 2001' Rogaśka s]aiina, APri] 2001. 13. Catjć I', ol]ić R': PJi7sli/ i ś]l,n'1989' 8, 1' 11. Catić l' .t S,vstem Ana]vsis and MorPhologica] 'j': of Nloulds lor Injection \'louldhg. Classification 31h Annual N'Ie€ling of the Pol\'mer Proccssins So c,ietv, St ttg.rt 1987, p. L-24. 15. catić 1', Raz1N'' Raos P.: "s)'stenjc AnaL,vsis of In' jeciion N'Iou1ding of Po]\'rn€Is", Druśt\'oP1asiićala i,tumaraca, Zatreb 1991. catić ]': (llrlststoff. 197i, 65, 123' Rec,:i Re1,i..L1 ?d t7 Vlll 2AA0. .ttsi." 6 MA01